【英文标准名称】:Chemicaltestsforrawandvulcanizedrubber-Methodsfordeterminationofaccelerators-Gasandthinlayerchromatography
【原文标准名称】:生橡胶和硫化橡胶的化学试验.加速器测定方法.气相和薄层色谱法
【标准号】:BS7164-32.1-1998
【标准状态】:现行
【国别】:英国
【发布日期】:1998-10-15
【实施或试行日期】:1998-10-15
【发布单位】:英国标准学会(BSI)
【起草单位】:BSI
【标准类型】:()
【标准水平】:()
【中文主题词】:定性分析;催速剂(化学);色谱法;硫化橡胶;含量测定;酰胺;气相色谱法;胍;试验条件;化学分析和试验;薄层色谱法;胺(脂族);噻唑;硫有机化合物;胺(芳族);硬化材料;吗啉;试样制备
【英文主题词】:Accelerators(chemical);Chemicalanalysisandtesting;Determinationofcontent;Gaschromatography;Identification;Rubber;Rubbercompounds;Vulcanizatedrubber;Vulcanizationaccelerators
【摘要】:1ThisInternationalStandardspecifiesmethodsusinggaschromatography(GC)andthinlayerchromatography(TLC)fortheseparationandidentificationofthefollowingclassesofacceleratorsinvulcanizedandunvulcanizedcompounds:—thiazoles—sulfenamides—thiuramsanddithiocarbamates—guanidines—dithiodimorpholine2When2-mercaptobenzothiazole(MBT)isidentifiedandnosulfenamidesarepresent,itisnotpossibletoestablishiftheoriginalacceleratorwasMBTand/oritssaltsor2,2'-dibenzothiazoledisulfide(MBTS)aseachoftheseacceleratorsmaybeproducedfromtheothersduringthevulcanizationprocess.3Whensulfenamidesareidentified,itisnotpossibletoestablishifMBTand/oritssaltsandMBTSarepresentastheseacceleratorsmaybeproducedfrom2-mercaptobenzothiazolesulfenamidesduringthevulcanizationprocess.4Themethodsdonotdistinguishthiuramsanddithiocarbamatesderivedfromthesameamines.5Fromthemorpholineidentificationitisnotpossibletodetermineiftheinitialacceleratoris2-morpholinothio-benzothiazole(MBS)ordithiomorpholineasmorpholinemaybeformedfromMBSanddithiodimorpholineduringthevulcanizationprocess.6Theseparationofacceleratorcompoundsfromunvulcanizedcompoundsisrelativelystraightforwardwhereasseparationfromvulcanizedcompoundsisdifficultduetothelesserabilityofsolventstopenetratethevulcanizedmatrix.7SomecompoundingingredientsmayinterferewithmethodB.InsuchcasesmethodsAorCshallbeused.
【中国标准分类号】:G34
【国际标准分类号】:83_060
【页数】:16P;A4
【正文语种】:英语